Column 1 | Column 2 | Column 3 | Column 4 | Column 5 | |
Item | Description of hazardous chemical | Placard quantity | Manifest quantity | ||
1 | Flammable gases | Category 1A, category 1B or any combination of categories 1A and 1B | 200L | 5,000L | |
2 | Gases under pressure | With acute toxicity, categories 1, 2, 3 or 4 | 50L | 500L | |
3 | With skin corrosion, categories 1A, 1B or 1C | 50L | 500L | ||
4 | Aerosols category 1, category 2, category 3 or any combination of categories 1, 2 and 3 | 5,000L | 10,000L | ||
5 | Not stated elsewhere in this table | 1,000L | 10,000L | ||
6 | Flammable liquids | Category 1 | 50L | 500L | |
7 | Category 2 | 250L | 2,500L | ||
8 | Category 3 | 1,000L | 10,000L | ||
9 | Any combination of chemicals from items 6 to 8 where none of the items exceeds the quantities in columns 4 or 5 on their own | 1,000L | 10,000L | ||
10 | Category 4 | 10,000L | 100,000L | ||
11 | Self-reactive substances | Type A | 5kg or 5L | 50kg or 50L | |
12 | Type B | 50kg or 50L | 500kg or 500L | ||
13 | Type C to F | 250kg or 250L | 2,500kg or 2,500L | ||
14 | Flammable solids | Category 1 | 250kg | 2,500kg | |
15 | Category 2 | 1,000kg | 10,000kg | ||
16 | Any combination of chemicals from items 12 to 15 where none of the items exceeds the quantities in columns 4 or 5 on their own | 1,000kg or 1,000L | 10,000kg or 10,000L | ||
17 | Pyrophoric liquids and pyrophoric solids | Category 1 | 50kg or 50L | 500kg or 500L | |
18 | Self-heating substances and mixtures | Category 1 | 250kg or 250L | 2,500kg or 2,500L | |
19 | Category 2 | 1,000kg or 1,000L | 10,000kg or 10,000L | ||
20 | Any combination of chemicals from items 17 to 19 where none of the items exceeds the quantities in columns 4 or 5 on their own | 1,000kg or 1,000L | 10,000kg or 10,000L | ||
21 | Substances which in contact with water emit flammable gas | Category 1 | 50kg or 50L | 500kg or 500L | |
22 | Category 2 | 250kg or 250L | 2,500kg or 2,500L | ||
23 | Category 3 | 1,000kg or 1,000L | 10,000kg or 10,000L | ||
24 | Any combination of chemicals from items 21 to 23 where none of the items exceeds the quantities in columns 4 or 5 on their own | 1,000kg or 1,000L | 10,000kg or 10,000L | ||
25 | Oxidising liquids and oxidising solids | Category 1 | 50kg or 50L | 500kg or 500L | |
26 | Category 2 | 250kg or 250L | 2,500kg or 2,500L | ||
27 | Category 3 | 1,000kg or 1,000L | 10,000kg or 10,000L | ||
28 | Any combination of chemicals from items 25 to 27 where none of the items exceeds the quantities in columns 4 or 5 on their own | 1,000kg or 1,000L | 10,000kg or 10,000L | ||
29 | Organic peroxides | Type A | 5kg or 5L | 50kg or 50L | |
30 | Type B | 50kg or 50L | 500kg or 500L | ||
31 | Type C to F | 250kg or 250L | 2,500kg or 2,500L | ||
32 | Any combination of chemicals from items 30 and 31 where none of the items exceeds the quantities in columns 4 or 5 on their own | 250kg or 250L | 2,500kg or 2,500L | ||
33 | Acute toxicity | Category 1 | 50kg or 50L | 500kg or 500L | |
34 | Category 2 | 250kg or 250L | 2,500kg or 2,500L | ||
35 | Category 3 | 1,000kg or 1,000L | 10,000kg or 10,000L | ||
36 | Any combination of chemicals from items 33 to 35 where none of the items exceeds the quantities in columns 4 or 5 on their own | 1,000kg or 1,000L | 10,000kg or 10,000L | ||
37 | Skin corrosion | Category 1A | 50kg or 50L | 500kg or 500L | |
38 | Category 1B | 250kg or 250L | 2,500kg or 2,500L | ||
39 | Category 1C | 1,000kg or 1,000L | 10,000kg or 10,000L | ||
40 | Corrosive to metals | Category 1 | 1,000kg or 1,000L | 10,000kg or 10,000L | |
41 | Any combination of chemicals from items 37 to 40 where none of the items exceeds the quantities in columns 4 or 5 on their own | 1,000kg or 1,000L | 10,000kg or 10,000L | ||
42 | Unstable explosives | 5kg or 5L | 50kg or 50L | ||
43 | Unstable chemicals | Any combination of chemicals from items 11, 29 and 42 where none of the items exceeds the quantities in columns 4 or 5 on their own | 5kg or 5L | 50kg or 50L |
Notes—1 In item 2, Gases under pressure with acute toxicity, category 4 only applies up to a LC50 of 5,000 ppmV. This is equivalent to dangerous goods of Division 2.3 .2 Item 4 includes flammable aerosols.
For this table, if a flammable liquid category 4 is used, handled or stored in the same spill compound as one or more flammable liquids of categories 1, 2 or 3, the total quantity of flammable liquids categories 1, 2 or 3 must be determined as if the flammable liquid category 4 had the same classification as the flammable liquid in the spill compound with the lowest flash point.
Example—For placarding and manifest purposes, a spill compound containing 1,000L of flammable liquid category 1 and 1,000L of flammable liquid category 4 is considered to contain 2,000L of flammable liquid category 1.